TRIUMF

Exp. No.

M1592 — Approved

Title of Experiment

Muoniated free radicals containing phosphorus

Spokesperson(s) for Group

Safety Coordinator(s) for Group

Current Members of Group

Name Institution Status % of research time devoted to experiment
P.W. Percival Simon Fraser University Professor
L. Chandrasena Simon Fraser University Student (PhD)
Mina M. Simon Fraser University Student (PhD)
I. McKenzie TRIUMF Research Scientist
K. Samedov University of British Columbia PDF
R. West University of Wisconsin Professor

Abstract

We are studying free radicals formed by muonium addition to organophosphorus compounds. The equivalent radicals containing H are short-lived and in general can not be detected by more conventional means. Detecting and identifying the muoniated radicals tells us about the reaction mechanisms of novel materials being used as new synthetic reagents, catalysts, and polymerization initiators.